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- W4246400921 abstract "The mechanism of film formation and crosslinking in a poly(methyl methacrylate/n-butyl acrylate/TMI®) (PMBT) and amino-telechelic polybutadiene (PBD-NH2) latex blend was studied. Films cast from the latex blends were ultramicrotomed and examined by transmission electron microscopy. The PBD-NH2 was found to be located primarily at the surface of the PMBT particles due to a crosslinking reaction. Without the possibility of crosslinking (when TMI was absent in the acrylic copolymer), the PBD-NH2 only formed segregated phases in the acrylic polymer matrix due to the incompatibility of the two polymers. While this PBD-NH2 could be extracted with toluene, the PBD-NH2 crosslinked at the PMBT particle surfaces was not extractable. FTIR results showed that the isocyanate groups in the PMBT were completely consumed when the PBD-NH2 concentration was sufficiently high, indicating that the PBD-NH2 had diffused and reacted inside the PMBT particles. Thus, the crosslinking reaction was considered to be the driving force for the diffusion of the PBD-NH2 into the PMBT particles. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 977–984, 1998" @default.
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- W4246400921 date "1998-08-01" @default.
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- W4246400921 title "Crosslinking of isocyanate functional acrylic latex with telechelic polybutadiene. II. Film formation/crosslinking" @default.
- W4246400921 doi "https://doi.org/10.1002/(sici)1097-4628(19980801)69:5<977::aid-app17>3.3.co;2-4" @default.
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