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- W4246437400 abstract "Spannungsabbau: Die erste breit anwendbare, katalytische und stereoselektive Vinyloxiran-Ringerweiterung wird beschrieben (siehe Schema; hfacac=Hexafluoracetylacetonat). Die Stereoselektivität wird durch etliche Reaktionsparameter beeinflusst, und kinetische Studien sprechen für die In-situ-Bildung einer katalytisch aktiven Spezies. Die Reaktion wurde in der asymmetrischen Totalsynthese von (+)-Goniothalesdiol eingesetzt. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4246437400 date "2010-02-04" @default.
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- W4246437400 title "Stereoselective Ring Expansion of Vinyl Oxiranes: Mechanistic Insights and Natural Product Total Synthesis" @default.
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