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- W4246445212 abstract "Abstract Hemithioindigo molecular motors undergo very fast unidirectional rotation upon irradiation with visible light, which has prevented a complete analysis of their working mechanism. In this work, we have considerably slowed down their motion by using a new synthesis for sterically hindered motor derivatives. This method allowed the first observation of all four intermediate states populated during rotation. The exact order in which each isomeric state is formed under irradiation conditions was elucidated using low temperature 1 H NMR spectroscopy in conjunction with other analytical methods. At the same time, complete unidirectionality could also be directly shown. Access to slowly rotating hemithioindigo motors opens up a plethora of new applications for visible‐light‐induced unidirectional motions, especially in areas such as catalysis, smart materials, and supramolecular chemistry." @default.
- W4246445212 created "2022-05-12" @default.
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- W4246445212 date "2017-10-12" @default.
- W4246445212 modified "2023-10-16" @default.
- W4246445212 title "Direct Observation of Hemithioindigo‐Motor Unidirectionality" @default.
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- W4246445212 doi "https://doi.org/10.1002/ange.201708178" @default.
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