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- W4246456870 abstract "For a simple dissociation equilibrium the equilibrium constant K p at temperature T can be written in terms of partial pressures p or densities n in the form given by Equation 6 of Tatum (1966) where m is the reduced mass of AB, k the Boltzmann constant, h the Planck constant, Q A , Q B , Q AB the internal partition functions of the species, and D 0 the dissociation energy of AB. This equation derives from a more general expression of K p ( T ) for a chemical reaction that is demonstrated in all physicalchemistry textbooks treating statistical thermodynamics (see for example Atkins 1990). Partition functions are weighted Boltzmann factors with ϵ n corresponding to the energy of the eigenstates of degeneracy g n . Provided all the eigenvalues are known, Q values can be calculated exactly. Derivations and calculations of the partition functions can be found in textbooks or in reviews relating to astrophysics." @default.
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- W4246456870 title "Dissociation Energies and Partition Functions of Small Molecules" @default.
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- W4246456870 doi "https://doi.org/10.1017/s0252921100021370" @default.
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