Matches in SemOpenAlex for { <https://semopenalex.org/work/W4246458195> ?p ?o ?g. }
- W4246458195 endingPage "13013" @default.
- W4246458195 startingPage "13007" @default.
- W4246458195 abstract "Abstract Surface ligands play critical roles in determining the surface properties of metal clusters. However, modulating the properties and controlling the surface structure of clusters through surface‐capping‐agent displacement is challenging. Herein, [Ag 14 (SPh(CF 3 ) 2 ) 12 (PPh 3 ) 4 (DMF) 4 ] ( Ag 14 ‐DMF ; DMF= N , N ‐dimethylformamide), with weakly coordinated DMF ligands on surface silver sites, was synthesized by a mixed‐ligands strategy. Owing to the high surface reactivity of Ag 14 ‐DMF , the surface ligands are labile, easily dissociated or exchanged by other ligands. Based on the enhanced surface reactivity, easy modulation of the optical properties of Ag 14 by reversible “on‐off” DMF ligation was realized. When chiral amines were introduced to as‐prepared products, all eight surface ligands were replaced by amines and the racemic Ag 14 clusters were converted to optically pure homochiral Ag 14 clusters as evidenced by circular dichroism (CD) activity and single‐crystal X‐ray diffraction (SCXRD). This work provides a new insight into modulation of the optical properties of metal clusters and atomically precise homochiral clusters for specific applications are obtained." @default.
- W4246458195 created "2022-05-12" @default.
- W4246458195 creator A5012829280 @default.
- W4246458195 creator A5020046323 @default.
- W4246458195 creator A5034678508 @default.
- W4246458195 creator A5056791108 @default.
- W4246458195 creator A5057908998 @default.
- W4246458195 creator A5069825601 @default.
- W4246458195 creator A5080100993 @default.
- W4246458195 date "2021-04-28" @default.
- W4246458195 modified "2023-10-16" @default.
- W4246458195 title "Enhanced Surface Ligands Reactivity of Metal Clusters by Bulky Ligands for Controlling Optical and Chiral Properties" @default.
- W4246458195 cites W1981995472 @default.
- W4246458195 cites W1986543724 @default.
- W4246458195 cites W2012401131 @default.
- W4246458195 cites W2028178195 @default.
- W4246458195 cites W2032076075 @default.
- W4246458195 cites W2064441640 @default.
- W4246458195 cites W2068625016 @default.
- W4246458195 cites W2103742141 @default.
- W4246458195 cites W2105544900 @default.
- W4246458195 cites W2116346346 @default.
- W4246458195 cites W2140537016 @default.
- W4246458195 cites W2141916182 @default.
- W4246458195 cites W2266564964 @default.
- W4246458195 cites W2314879976 @default.
- W4246458195 cites W2326749880 @default.
- W4246458195 cites W2332639255 @default.
- W4246458195 cites W2334642287 @default.
- W4246458195 cites W2501442735 @default.
- W4246458195 cites W2515286324 @default.
- W4246458195 cites W2540506670 @default.
- W4246458195 cites W2567271618 @default.
- W4246458195 cites W2604143043 @default.
- W4246458195 cites W2614866349 @default.
- W4246458195 cites W2623026738 @default.
- W4246458195 cites W2754732097 @default.
- W4246458195 cites W2766549389 @default.
- W4246458195 cites W2767938046 @default.
- W4246458195 cites W2778959544 @default.
- W4246458195 cites W2793992683 @default.
- W4246458195 cites W2801392051 @default.
- W4246458195 cites W2806394448 @default.
- W4246458195 cites W2893269882 @default.
- W4246458195 cites W2898993990 @default.
- W4246458195 cites W2901109410 @default.
- W4246458195 cites W2910376802 @default.
- W4246458195 cites W2917753515 @default.
- W4246458195 cites W2918612296 @default.
- W4246458195 cites W2918839979 @default.
- W4246458195 cites W2924152529 @default.
- W4246458195 cites W2924795774 @default.
- W4246458195 cites W2945677369 @default.
- W4246458195 cites W2970704366 @default.
- W4246458195 cites W2971791401 @default.
- W4246458195 cites W2972115592 @default.
- W4246458195 cites W2973048906 @default.
- W4246458195 cites W3085715563 @default.
- W4246458195 cites W3094604174 @default.
- W4246458195 cites W4231411378 @default.
- W4246458195 cites W4232149353 @default.
- W4246458195 cites W4239841534 @default.
- W4246458195 cites W4248809306 @default.
- W4246458195 cites W4251512202 @default.
- W4246458195 cites W4252499873 @default.
- W4246458195 cites W4253820785 @default.
- W4246458195 doi "https://doi.org/10.1002/ange.202101141" @default.
- W4246458195 hasPublicationYear "2021" @default.
- W4246458195 type Work @default.
- W4246458195 citedByCount "4" @default.
- W4246458195 countsByYear W42464581952022 @default.
- W4246458195 countsByYear W42464581952023 @default.
- W4246458195 crossrefType "journal-article" @default.
- W4246458195 hasAuthorship W4246458195A5012829280 @default.
- W4246458195 hasAuthorship W4246458195A5020046323 @default.
- W4246458195 hasAuthorship W4246458195A5034678508 @default.
- W4246458195 hasAuthorship W4246458195A5056791108 @default.
- W4246458195 hasAuthorship W4246458195A5057908998 @default.
- W4246458195 hasAuthorship W4246458195A5069825601 @default.
- W4246458195 hasAuthorship W4246458195A5080100993 @default.
- W4246458195 hasBestOaLocation W42464581952 @default.
- W4246458195 hasConcept C115537861 @default.
- W4246458195 hasConcept C133571119 @default.
- W4246458195 hasConcept C142724271 @default.
- W4246458195 hasConcept C147789679 @default.
- W4246458195 hasConcept C178790620 @default.
- W4246458195 hasConcept C179104552 @default.
- W4246458195 hasConcept C185592680 @default.
- W4246458195 hasConcept C204787440 @default.
- W4246458195 hasConcept C2776910235 @default.
- W4246458195 hasConcept C2777712214 @default.
- W4246458195 hasConcept C2780471494 @default.
- W4246458195 hasConcept C544153396 @default.
- W4246458195 hasConcept C70862543 @default.
- W4246458195 hasConcept C71924100 @default.
- W4246458195 hasConcept C73922627 @default.
- W4246458195 hasConcept C8010536 @default.
- W4246458195 hasConceptScore W4246458195C115537861 @default.