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- W4246497974 abstract "The synthesis and chemistry of compounds containing the O-F moiety not attached to perfluorinated alkyl group are described. In general such compounds are less stable than their perfluoroalkyl counterparts. With the exception of AcOF, they should possess at least one electron withdrawing group α to the O-F moiety. It was found that the bigger the alkyl chain of these derivatives the less stable is the compound itself. HOF is also a member of this group and when stabilized by acetonitrile it can perform efficient epoxidation, as well as tertiary hydroxylation on remote and deactivated sites. It also provides an easy way for incorporating various oxygen isotopes such as 18O into organic molecules." @default.
- W4246497974 created "2022-05-12" @default.
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- W4246497974 date "1991-02-22" @default.
- W4246497974 modified "2023-09-25" @default.
- W4246497974 title "New Oxidants Containing the O-F Moiety and Some of Their Uses in Organic Chemistry" @default.
- W4246497974 doi "https://doi.org/10.1021/bk-1991-0456.ch004" @default.
- W4246497974 hasPublicationYear "1991" @default.
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