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- W4246686570 abstract "The equilibria and kinetics of the reaction of Pd(gly)2 complexes with hydrogen ions and chloride ions has been studied by a potentiometric method. The underlying idea of the method is the measurement of solution pH as a function of reaction time t using a glass electrode. The solutions used had the following initial compositions: xM Pd(gly)2, xM Hgly, and 1 M NaCl with x = 1 × 10−4, 5 × 10−4, and 1 × 10−3; initial pH0 was from ∼3.5 to ∼4.4. The experimentally determined pH versus t dependences and the rate equation for a pseudo-second-order reaction were used to determine the equilibrium constant of formation of Pd(gly)(Hgly)Cl complexes from Pd(gly)2 complexes and the observed rate constant for this reaction, k obs. The dependence of k obs on the pH of the acid solutions studied was assigned to a change in the sequence of the reactions of addition of a hydrogen ion and a chloride ion to the complex Pd(gly)2." @default.
- W4246686570 created "2022-05-12" @default.
- W4246686570 date "2010-01-01" @default.
- W4246686570 modified "2023-10-14" @default.
- W4246686570 title "10.1007/s11175-008-3002-5" @default.
- W4246686570 doi "https://doi.org/10.1007/s11175-008-3002-5" @default.
- W4246686570 hasPublicationYear "2010" @default.
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