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- W4246699286 abstract "A new monomer, methoxyitaconyl-5-fluorouracil (MITFU), was synthesized by the reaction of 5-fluorouracil (5-FU) and methoxyitaconyl chloride. The homopolymers of MITFU and exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride and their copolymers with acrylic acid and/or vinyl acetate were prepared by the photopolymerizations. The synthesized MITFU and polymers were identified by Fourier transform infrared and 1H nuclear magnetic resonance spectroscopies. The contents of MITFU in poly(MITFU–co–AA) and poly(MITFU–co–VAc) determined by elemental analysis were 45 and 72 mol%, respectively. The weight average molecular weights determined by gel permeation chromatography were in the range of 7200 to 16,500. The in vitro cytotoxicities of samples were evaluated with mouse mammary carcinoma (FM3A), mouse leukemia (P388) and human histiocytic lymphoma (U937) as cancer cell lines. The in vivo antitumor activities of synthesized polymers against mice bearing the sarcoma 180 tumor cell line were greater than those of 5-FU at concentrations of 0.8 and 80 mg/kg. © 1997 John Wiley & Sons, Ltd." @default.
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- W4246699286 date "1997-11-01" @default.
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- W4246699286 title "Synthesis and biological activities of polymers containing pyrimidine or carboxyl Group" @default.
- W4246699286 doi "https://doi.org/10.1002/(sici)1099-1581(199711)8:11<701::aid-pat704>3.3.co;2-8" @default.
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