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- W4246702921 abstract "This chapter is devoted to electrochemical processes in which chemical reactions accompany the initial transfer of one electron. It reviews successively the main reaction schemes that associate electron transfers with chemical steps, with the objective of diagnosing their occurrence and determining their thermodynamic and kinetic characteristics. The main technique that is used in this purpose is cyclic voltammetry. The chapter contains a description of the various methods than can be used for computing the current-potential responses and a discussion of the use of diagnostic criteria and working curves in mechanism and kinetic analyses. It addresses a completely different domain, viz., preparative-scale electrolysis and illustrates the general principles and theoretical analyses by selected experimental examples. The chapter also focuses on redox properties of transient radicals and compares the electrochemical approach with a series of nonelectrochemical approaches. It discusses the dichotomy between radical and ionic chemistry triggered after an initial electron transfer." @default.
- W4246702921 created "2022-05-12" @default.
- W4246702921 date "2019-06-18" @default.
- W4246702921 modified "2023-10-16" @default.
- W4246702921 title "Coupling of Electrode Electron Transfers with Homogeneous Chemical Reactions" @default.
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- W4246702921 doi "https://doi.org/10.1002/9781119292364.ch2" @default.
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