Matches in SemOpenAlex for { <https://semopenalex.org/work/W4246758732> ?p ?o ?g. }
- W4246758732 endingPage "17008" @default.
- W4246758732 startingPage "17000" @default.
- W4246758732 abstract "XeAuF has been detected and characterized using microwave rotational spectroscopy. It was prepared by laser ablation of Au in the presence of Xe and SF6, and stabilized in a supersonic jet of Ar. The spectrum was measured with a cavity pulsed jet Fourier transform microwave spectrometer, in the frequency range 6−26 GHz. Rotational constants, centrifugal distortion constants, and 131Xe and 197Au nuclear quadrupole coupling constants have been evaluated. The molecule is linear, with a short XeAu bond (2.54 Å), and is rigid. The 131Xe nuclear quadrupole coupling constant (NQCC) is large (−135 MHz). The 197Au NQCC differs radically from that of uncomplexed AuF. The results are supported by those of ab initio calculations which have given an XeAu dissociation energy ∼100 kJ mol-1, plus Mulliken and natural bond orbital populations, MOLDEN plots of valence orbitals, and an energy density distribution. All evidence is consistent with XeAu covalent bonding in XeAuF." @default.
- W4246758732 created "2022-05-12" @default.
- W4246758732 creator A5004472184 @default.
- W4246758732 creator A5052305239 @default.
- W4246758732 date "2004-12-01" @default.
- W4246758732 modified "2023-10-11" @default.
- W4246758732 title "XeAuF" @default.
- W4246758732 cites W1535755650 @default.
- W4246758732 cites W1665393863 @default.
- W4246758732 cites W1963486098 @default.
- W4246758732 cites W1964172939 @default.
- W4246758732 cites W1970241448 @default.
- W4246758732 cites W1971589819 @default.
- W4246758732 cites W1977325685 @default.
- W4246758732 cites W1978755937 @default.
- W4246758732 cites W1982268415 @default.
- W4246758732 cites W1983652192 @default.
- W4246758732 cites W1992723173 @default.
- W4246758732 cites W1998270541 @default.
- W4246758732 cites W2003961474 @default.
- W4246758732 cites W2017063616 @default.
- W4246758732 cites W2017951783 @default.
- W4246758732 cites W2020664780 @default.
- W4246758732 cites W2030442197 @default.
- W4246758732 cites W2032768104 @default.
- W4246758732 cites W2033844788 @default.
- W4246758732 cites W2035370712 @default.
- W4246758732 cites W2038376465 @default.
- W4246758732 cites W2038714995 @default.
- W4246758732 cites W2043271945 @default.
- W4246758732 cites W2043554702 @default.
- W4246758732 cites W2050076732 @default.
- W4246758732 cites W2053673174 @default.
- W4246758732 cites W2053895533 @default.
- W4246758732 cites W2060395367 @default.
- W4246758732 cites W2069723789 @default.
- W4246758732 cites W2071631490 @default.
- W4246758732 cites W2073280539 @default.
- W4246758732 cites W2077386898 @default.
- W4246758732 cites W2079202661 @default.
- W4246758732 cites W2085786597 @default.
- W4246758732 cites W2094632059 @default.
- W4246758732 cites W2102039279 @default.
- W4246758732 cites W2107316264 @default.
- W4246758732 cites W2117916548 @default.
- W4246758732 cites W2129028579 @default.
- W4246758732 cites W2135261637 @default.
- W4246758732 cites W2136340798 @default.
- W4246758732 cites W2148941593 @default.
- W4246758732 cites W2152199532 @default.
- W4246758732 cites W2163692807 @default.
- W4246758732 cites W2278651110 @default.
- W4246758732 cites W2949703534 @default.
- W4246758732 cites W2949893438 @default.
- W4246758732 cites W4230176342 @default.
- W4246758732 cites W4232180739 @default.
- W4246758732 doi "https://doi.org/10.1021/ja044955j" @default.
- W4246758732 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15612738" @default.
- W4246758732 hasPublicationYear "2004" @default.
- W4246758732 type Work @default.
- W4246758732 citedByCount "166" @default.
- W4246758732 countsByYear W42467587322012 @default.
- W4246758732 countsByYear W42467587322013 @default.
- W4246758732 countsByYear W42467587322014 @default.
- W4246758732 countsByYear W42467587322015 @default.
- W4246758732 countsByYear W42467587322016 @default.
- W4246758732 countsByYear W42467587322017 @default.
- W4246758732 countsByYear W42467587322018 @default.
- W4246758732 countsByYear W42467587322019 @default.
- W4246758732 countsByYear W42467587322020 @default.
- W4246758732 countsByYear W42467587322021 @default.
- W4246758732 countsByYear W42467587322022 @default.
- W4246758732 countsByYear W42467587322023 @default.
- W4246758732 crossrefType "journal-article" @default.
- W4246758732 hasAuthorship W4246758732A5004472184 @default.
- W4246758732 hasAuthorship W4246758732A5052305239 @default.
- W4246758732 hasConcept C102931765 @default.
- W4246758732 hasConcept C109214941 @default.
- W4246758732 hasConcept C121332964 @default.
- W4246758732 hasConcept C122032599 @default.
- W4246758732 hasConcept C147789679 @default.
- W4246758732 hasConcept C178790620 @default.
- W4246758732 hasConcept C183276030 @default.
- W4246758732 hasConcept C184779094 @default.
- W4246758732 hasConcept C185592680 @default.
- W4246758732 hasConcept C2781442258 @default.
- W4246758732 hasConcept C31100168 @default.
- W4246758732 hasConcept C32909587 @default.
- W4246758732 hasConcept C39984356 @default.
- W4246758732 hasConcept C41999313 @default.
- W4246758732 hasConcept C62396407 @default.
- W4246758732 hasConceptScore W4246758732C102931765 @default.
- W4246758732 hasConceptScore W4246758732C109214941 @default.
- W4246758732 hasConceptScore W4246758732C121332964 @default.
- W4246758732 hasConceptScore W4246758732C122032599 @default.
- W4246758732 hasConceptScore W4246758732C147789679 @default.
- W4246758732 hasConceptScore W4246758732C178790620 @default.
- W4246758732 hasConceptScore W4246758732C183276030 @default.