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- W4246768215 abstract "3D well-crystallized metal–organic frameworks (MOFs), M-THBQ (M=Fe, Co, Mn, THBQ=tetrahydroxybenzoquinone), are synthesized and characterized. Their structures are determined as cubic cell in the group of Pm from powder X-ray diffraction data, and their properties of electronic, magnetic and spectroscopic are also investigated. They are all semiconductors, and Fe-THBQ exhibits the air-stable n-type thermoelectric characteristic as its Seebeck coefficient reaches −130 μV K−1, and the electrical conductivity is 2.7×10−4 S cm−1 at 300 K. Additional, M-THBQ are paramagnetic, and the value of Weiss constant of Fe-THBQ is −219.37 K, indicating the existence of robust intramolecular antiferromagnetic exchanges. Meanwhile, they display strong absorption bands in the range of 220 to 1000 nm, suggest M-THBQ could have the potential to become photoabsorbers, and Fe-THBQ exhibits a narrow band gap of 0.63 eV according to the ultraviolet absorption edge spectrum." @default.
- W4246768215 created "2022-05-12" @default.
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- W4246768215 date "2020-09-08" @default.
- W4246768215 modified "2023-10-15" @default.
- W4246768215 title "Paramagnetic Conducting Metal–Organic Frameworks with Three‐Dimensional Structure" @default.
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- W4246768215 doi "https://doi.org/10.1002/ange.202009253" @default.
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