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- W4246768388 abstract "Abstract A μ 3 ‐η 2 :η 2 :η 2 ‐silane complex, [(Cp*Ru) 3 (μ 3 ‐η 2 :η 2 :η 2 ‐H 3 Si t Bu)(μ‐H) 3 ] ( 2 a ; Cp*=η 5 ‐C 5 Me 5 ), was synthesized from the reaction of [{Cp*Ru(μ‐H)} 3 (μ 3 ‐H) 2 ] ( 1 ) with t BuSiH 3 . Complex 2 a is the first example of a silane ligand adopting a μ 3 ‐η 2 :η 2 :η 2 coordination mode. This unprecedented coordination mode was established by NMR and IR spectroscopy as well as X‐ray diffraction analysis and supported by a density functional study. Variable‐temperature NMR analysis implied that 2 a equilibrates with a tautomeric μ 3 ‐silyl complex ( 3 a ). Although 3 a was not isolated, the corresponding μ 3 ‐silyl complex, [(Cp*Ru) 3 (μ 3 ‐η 2 :η 2 ‐H 2 SiPh)(H)(μ‐H) 3 ] ( 3 b ), was obtained from the reaction of 1 with PhSiH 3 . Treatment of 2 a with PhSiH 3 resulted in a silane exchange reaction, leading to the formation of 3 b accompanied by the elimination of t BuSiH 3 . This result indicates that the μ 3 ‐silane complex can be regarded as an “arrested” intermediate for the oxidative addition/reductive elimination of a primary silane to a trinuclear site." @default.
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- W4246768388 date "2015-10-21" @default.
- W4246768388 modified "2023-09-23" @default.
- W4246768388 title "μ 3 ‐η 2 :η 2 :η 2 ‐Coordination of Primary Silane on a Triruthenium Plane" @default.
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- W4246768388 doi "https://doi.org/10.1002/ange.201506969" @default.
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