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- W4246775352 abstract "A new study of 12CH4 line positions and intensities was performed for part of the Tetradecad region between 5300 and 5550 cm−1 using four long path (202 m, 602 m, 1604 m and 1804 m) spectra of normal samples of CH4 at different pressures recorded with a Fourier transform spectrometer in Reims, France. Line positions and intensities were retrieved by least square curve-fitting procedures and analyzed using the effective Hamiltonian and the effective dipole moment expressed in terms of irreducible tensor operators adapted to spherical top molecules. An 80 K spectrum from JPL of enriched 12CH4 was used for low-J line positions. One other 80 K spectrum from JPL of enriched 13CH4 was used to discern the isotopic lines. A new measured linelist contains positions and intensities for 5934 features. Quantum assignments were made for 2847 transitions, which represent ∼90% of the integrated line intensity observed in this region. All assigned line positions and 2227 selected line intensities were fitted with RMS standard deviations of 0.0025 cm−1 and 8.6%, respectively. The sum of observed intensities between 5300 and 5550 cm−1 fell within 2% of the predicted value from ab initio variational calculations." @default.
- W4246775352 created "2022-05-12" @default.
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- W4246775352 date "2017-11-01" @default.
- W4246775352 modified "2023-09-30" @default.
- W4246775352 title "Measurements and modeling of long-path 12CH4 spectra in the 5300–5550 cm−1 region" @default.
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- W4246775352 doi "https://doi.org/10.1016/j.jqsrt.2017.07.030" @default.
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