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- W4246777184 abstract "Novel neutral hexacoordinate silicon complexes 1-6 were prepared and the mechanism of ligand exchange studied. Two simultaneous nondissociative N-methyl exchange processes were found. On the basis of persistence of 1JSi-F and 2JN-Si-H in 5 and 1a, respectively, dissociative exchange was ruled out. The two consecutive processes were assigned (in order of increasing activation energy) to (X, Cl)- and (O, O)-1,2-shifts, based on the low-temperature NOESY and Saturation Transfer spectrum. The first observation of 15N1H coupling across the Si-N coordinative bond is reported." @default.
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- W4246777184 date "2005-07-26" @default.
- W4246777184 modified "2023-10-03" @default.
- W4246777184 title "Ligand Exchange Mechanism in Novel Hexacoordinate Silicon Complexes" @default.
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- W4246777184 doi "https://doi.org/10.1002/9783527620777.ch73b" @default.
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