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- W4246823238 endingPage "12047" @default.
- W4246823238 startingPage "12043" @default.
- W4246823238 abstract "We report halogenated pentanidiums as phase-transfer catalysts for the asymmetric alkylation of sulfenate anions to various sulfoxides with high enantioselectivities (up to 99 % ee) and yields (up to 99 %). This approach gives access to enantioenriched heterocyclic sulfoxides that might not be compatible with strong oxidants or organometallic reagents. Computational studies have revealed that the multiple noncovalent interactions such as halogen bonds and nonclassical hydrogen bonds are involved." @default.
- W4246823238 created "2022-05-12" @default.
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- W4246823238 creator A5017162812 @default.
- W4246823238 creator A5021801739 @default.
- W4246823238 date "2014-09-10" @default.
- W4246823238 modified "2023-10-18" @default.
- W4246823238 title "Catalytic Enantioselective Alkylation of Sulfenate Anions to Chiral Heterocyclic Sulfoxides Using Halogenated Pentanidium Salts" @default.
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- W4246823238 doi "https://doi.org/10.1002/ange.201407512" @default.
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