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- W4246850619 abstract "Two types of Pd(II) complexes (B and C) of hydrazides of aspartic and glutamic acids were synthesized and studied. The type B complexes are of the general formula [Pd2(LH)2Cl2]X2 with two bridging chloride ions, where X = Cl− or OH− depending on the pH value. The ligands are bonded through the amino carboxylic NH2 group and the hydrazide oxygen, the carboxylic group being deprotonated and uncoordinated. In the type C complexes the ligands are bonded through a NH2 group and the deprotonated hydrazide nitrogen. At M:L = 1:1 and pH ∼ 2 the complexes again have the general content [Pd2(LH)2Cl2]Cl2, but with protonated carboxylic groups. At M:L = 1:2 two types of complexes C were synthesized, depending on the pH of the solution. At pH 2.50 mononuclear ionic complexes [Pd(LH)2Cl2]Cl2 are formed, with protonated carboxylic groups of the ligands, while at pH 3.50 the neutral species PdL2 are obtained with deprotonated carboxylic groups." @default.
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- W4246850619 date "1984-01-01" @default.
- W4246850619 modified "2023-09-27" @default.
- W4246850619 title "Palladium(II) complexes of hydrazides of aspartic and glutamic acids" @default.
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- W4246850619 doi "https://doi.org/10.1016/s0020-1693(00)88738-1" @default.
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