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- W4246936211 abstract "It has been established that a cationic rhodium(I)/H8-binap complex catalyzes the [3+2+2] cycloaddition of 1,6-diynes with cyclopropylideneacetamides to produce cycloheptadiene derivatives through cleavage of cyclopropane rings. In contrast, a cationic rhodium(I)/(S)-binap complex catalyzes the enantioselective [2+2+2] cycloaddition of terminal alkynes, acetylenedicarboxylates, and cyclopropylideneacetamides to produce spiro-cyclohexadiene derivatives which retain the cyclopropane rings." @default.
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- W4246936211 date "2015-06-01" @default.
- W4246936211 modified "2023-10-07" @default.
- W4246936211 title "Rhodium-Catalyzed [3+2+2] and [2+2+2] Cycloadditions of Two Alkynes with Cyclopropylideneacetamides" @default.
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- W4246936211 doi "https://doi.org/10.1002/ange.201502505" @default.
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