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- W4246964628 abstract "On the basis of the results of quantum-mechanical investigations a model system, 1, is suggested which allows the synthesis and the investigation of highly electrophilic silyl cationic species. The cations 1 are stabilized by intramolecular interaction with different electron-rich donor substituents X in a constant molecular environment. This model provides the possibility to compare the different stabilizing ability of the ligands X, which is the first step on the way to silyl cations with controlled and tunable reactivity. The applicability of this model system is demonstrated for three different stabilizing groups X (X = aryl, alkynyl and hydrogen)." @default.
- W4246964628 created "2022-05-12" @default.
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- W4246964628 date "2003-09-26" @default.
- W4246964628 modified "2023-10-14" @default.
- W4246964628 title "A Model System for the Generation of Silyl Cationic Species of Different Reactivity and Stability" @default.
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- W4246964628 doi "https://doi.org/10.1002/9783527619924.ch7" @default.
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