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- W4247017104 abstract "Abstract Treatment of pyridine‐stabilized silylene complexes [(η 5 ‐C 5 Me 4 R)(CO) 2 (H)WSiH(py)(Tsi)] (R=Me, Et; py=pyridine; Tsi=C(SiMe 3 ) 3 ) with an N‐heterocyclic carbene Me I i Pr (1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene) caused deprotonation to afford anionic silylene complexes [(η 5 ‐C 5 Me 4 R)(CO) 2 WSiH(Tsi)][H Me I i Pr] (R=Me ( 1‐Me ); R=Et ( 1‐Et )). Subsequent oxidation of 1‐Me and 1‐Et with pyridine‐ N ‐oxide (1 equiv) gave anionic η 2 ‐silaaldehydetungsten complexes [(η 5 ‐C 5 Me 4 R)(CO) 2 W{η 2 ‐OSiH(Tsi)}][H Me I i Pr] (R=Me ( 2‐Me ); R=Et ( 2‐Et )). The formation of an unprecedented W‐Si‐O three‐membered ring was confirmed by X‐ray crystal structure analysis." @default.
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- W4247017104 date "2015-11-24" @default.
- W4247017104 modified "2023-10-14" @default.
- W4247017104 title "Stabilization of a Silaaldehyde by its η<sup>2</sup> Coordination to Tungsten" @default.
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- W4247017104 doi "https://doi.org/10.1002/ange.201507956" @default.
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