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- W4247121934 abstract "The objectives of this work were to synthesize, characterize, and conduct a polymerization study on a set of ideal crosslinking monomers. The monomers studied are the three isomers of (2-vinyl-oxyethoxy)-β-nitrostyrene. Such monomers contain both the electron-donating vinyl ether moiety and the electron-accepting β-nitrostyrene moiety. A study of the spectral properties of these monomers was carried out in an effort to determine whether there was a contribution to the structure through an intramolecular interaction of the nature of a charge-transfer complex. Such studies have led to little or no support for such an interaction. As model compounds for comparison of spectral properties, the monomer series, o-, m-, and p-(2-ethoxyethoxy)-β-nitrostyrenes were synthesized and characterized as above. A comparison of the spectral and physical properties of these two series of compounds show that there are significant differences suggestive of the interactions proposed. However, since these discrepancies are small in most cases, it is not possible at present to correlate them specifically with the postulated intramolecular interactions." @default.
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- W4247121934 date "1978-06-01" @default.
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- W4247121934 title "Selective initiation of nonconjugated dienes containing electron donor–electron aceptor systems. I. Synthesis of vinyl ether–β-nitrostyrene monomers" @default.
- W4247121934 doi "https://doi.org/10.1002/pol.1978.170160615" @default.
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