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• W4247124512 startingPage "14481" @default.
• W4247124512 abstract "Abstract Methyl groups are ubiquitous in biologically active molecules. Thus, new tactics to introduce this alkyl fragment into polyfunctional structures are of significant interest. With this goal in mind, a direct method for the Markovnikov hydromethylation of alkenes is reported. This method exploits the degenerate metathesis reaction between the titanium methylidene unveiled from Cp 2 Ti(μ‐Cl)(μ‐CH 2 )AlMe 2 (Tebbe's reagent) and unactivated alkenes. Protonolysis of the resulting titanacyclobutanes in situ effects hydromethylation in a chemo‐, regio‐, and site‐selective manner. The broad utility of this method is demonstrated across a series of mono‐ and di‐substituted alkenes containing pendant alcohols, ethers, amides, carbamates, and basic amines." @default.
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• W4247124512 date "2021-05-19" @default.
• W4247124512 modified "2023-09-26" @default.
• W4247124512 title "Site‐Specific Alkene Hydromethylation via Protonolysis of Titanacyclobutanes" @default.
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• W4247124512 doi "https://doi.org/10.1002/ange.202103278" @default.
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