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- W4247177718 endingPage "920" @default.
- W4247177718 startingPage "915" @default.
- W4247177718 abstract "α-Hydroxyisobutyraldehyde, one of model compounds for α-aldol structure of streptose moiety of strpetomycin, was reduced at controlled-potential mercury cathode to give isobutyl alcohol and 1, 1-dimethylethyleneglycol. Reduction ratio of α-hydroxyl group was dependent on the cathode potential and pH, as was seen in the reduction of streptomycin. Results of reduction of α-hydroxyisobutyraldehyde with sodium or aluminum amalgam suggests that their mode of action on the aldehyde is determined by the magnitudes of negative potential that they respectively retain in the reaction media, and by pH, as in the cases of electroreduc-tion. Isobutyraldehyde was isolated as an intermediate product of reduction to isobutyl alcohol, in both cases." @default.
- W4247177718 created "2022-05-12" @default.
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- W4247177718 date "1961-01-01" @default.
- W4247177718 modified "2023-10-17" @default.
- W4247177718 title "Reduction of Aliphatic ^|^alpha;-Hydroxycarbonyl Compounds" @default.
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- W4247177718 doi "https://doi.org/10.1271/bbb1961.25.915" @default.
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