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- W4247208182 abstract "The Ne(3P00,2)+Xe+(5p5 2P01/2,3/2) excitation–transfer reaction has been studied by observing ultraviolet and visible emissions from Xe+* in a Ne flowing afterglow. The relative contribution of Xe+(2P03/2) and Xe+(2P01/2) to the excitation of Xe+* was examined by changing the [Xe+(2P01/2)]/[Xe+(2P03/2)] ratio with the addition of CH4 as a remover of the upper spin–orbit component. Since the intensity distribution of Xe+* lines was independent of the [Xe+(2P01/2)]/[Xe+(2P03/2)] ratio, it was concluded that the contribution of the Ne(3P00,2)+Xe+(2P01/2) reaction was insignificant. The Ne(3P00,2)+Xe+(2P03/2) reaction initially populates nine Xe+(6p,6p′,7s,6) levels in the 13.86–16.60 eV range. The favored product levels are 6p′ 2D03/2,5/2 and 7s 4P5/2 in the 16.36–16.43 eV range and 6p 4P05/2 at 13.88 eV, which are 0.2–0.3 and 2.7 eV below the entrance Ne(3P02)+Xe+(2P03/2) channel, respectively. The former near-resonant levels are excited by either direct curve crossings between attractive entrance potentials and flat exit ones or multiple curve crossings through a strongly attractive Ne−+Xe2+ ionic potential, while the latter nonresonant level is probably formed through the Ne−+Xe2+ ionic potential." @default.
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- W4247208182 date "1994-11-01" @default.
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- W4247208182 title "Electronic state distribution of Xe+* formed by excitation transfer from Ne(3<i>P</i>0,2) to Xe+(2<i>P</i>3/2) at thermal energy" @default.
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- W4247208182 doi "https://doi.org/10.1063/1.468498" @default.
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