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- W4247233624 abstract "Previously reported (J. Organomet. Chem., 246 (1983) 309) experimental data for the equilibrium constants and thermodynamic parameters of the reversible reaction 2 Rh2(CO)8 ⇄ Rh4(CO)12 + 4 CO have been re-evaluated using more reliable values for the solubility of carbon monoxide in hexane at lower than room temperature and introducing also a fugacity vs. pressure correction for carbon monoxide. The new values are: ΔH0 = 58.6 ± 10 kJ mol−1 and ΔS0 = 305 ± 25 J mol−1 K−1" @default.
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- W4247233624 date "1985-01-01" @default.
- W4247233624 modified "2023-10-03" @default.
- W4247233624 title "Fundamental metal carbonyl equilibria" @default.
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- W4247233624 doi "https://doi.org/10.1016/0022-328x(85)87043-1" @default.
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