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- W4247279679 abstract "Abstract One of the most efficient methodologies to prepare amines is the addition of organometallic reagents to imines. From a synthetic point of view, the corresponding allylation presents special interest due to the possible transformation of the introduced carbon‐carbon double bond into other functionalities. This addendum discusses the preparation of enantioenriched homoallylic primary amines. The most commonly used method to prepare the starting enantiomerically pure N‐tert ‐butylsulfinyl imines is the direct reaction of the corresponding carbonyl compounds with enantiomerically pure commercially available tert ‐butanesulfinamides and titanium tetraethoxide under thermal or microwave activation. The addendum also provides information on the synthetic applications of chiral N‐sulfinyl homoallylic amines." @default.
- W4247279679 created "2022-05-12" @default.
- W4247279679 creator A5040276834 @default.
- W4247279679 date "2020-04-29" @default.
- W4247279679 modified "2023-10-14" @default.
- W4247279679 title "Discussion Addendum for: Preparation of Enantioenriched Homoallylic Primary Amines" @default.
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- W4247279679 doi "https://doi.org/10.1002/0471264229.os096.12" @default.
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