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- W4247328899 abstract "The optical absorption and ESR spectra of Bi12GeO20 and B12SiO20 doped with Mn have been measured before and after illumination with visible light. Uniaxial stress measurements on a sharp line observed at 8026 cm−1 were performed. The observed ESR spectrum is a superposition of six lines resulting from the hyperfine interaction of manganese ions in tetrahedral positions. The g-factor and hyperfine constant are g = 1.999 ± 0.003 and A = 78 Gs. Analysis of the light-induced absorption spectrum leads to the conclusion that a small hole polaron bound to an Mn impurity at a tetrahedral site is responsible for the very broad absorption band which appears after illumination. The sharp line is interpreted as due to a transition inside the Mn+ center in tetrahedral coordination. Bands in the region 10,000–16,000 cm−1 are due to Mn3+ centers in interstitial positions, whose symmetry can be treated to a first approximation as tetragonal. The following crystal field parameters for this center were found: B = 565 cm−1, Dq = 1400 cm−1, Dt = −330 cm−1, Ds = 4170 cm−1 and C = 2260 cm−1. The illumination conditions which are needed for homogeneous coloration of the sample are also discussed." @default.
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- W4247328899 date "1985-01-01" @default.
- W4247328899 modified "2023-09-26" @default.
- W4247328899 title "Light-induced charge transfer processes in Mn-doped Bi12GeO20 and Bi12SiO20 single crystals" @default.
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- W4247328899 doi "https://doi.org/10.1016/0022-3697(85)90140-4" @default.
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