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- W4247409849 abstract "The effect of a sodium and sodium oxide overlayer on a Pd(100) surface has been investigated by AES, LEED, XPS, UPS and TPRS methods. Ordered surface structures of (4 × 4), (2 × 2) and c(2 × 2) were observed for a sodium overlayer, which was contracted by the adsorption of oxygen. The increase of bonding energy of CO, H2 as well as CO2 was confirmed on both sodium and sodium oxide covered surfaces, and three adsorption states were distinguished for CO2 on these surfaces. For the adsorption of methanol, formaldehyde and formic acid, the interaction was also strengthened on the sodium covered surface. As a result, the concentration as well as the stability of surface methoxide and formate was significantly increased and the strong interaction between formaldehyde and surface oxygen was confirmed." @default.
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- W4247409849 date "1986-11-01" @default.
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- W4247409849 title "Adsorption of methanol, formaldehyde and formic acid on Pd(100) surfaces modified by a sodium and sodium oxide overlayer" @default.
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- W4247409849 doi "https://doi.org/10.1016/0039-6028(86)90051-8" @default.
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