Matches in SemOpenAlex for { <https://semopenalex.org/work/W4247434047> ?p ?o ?g. }
- W4247434047 endingPage "5373" @default.
- W4247434047 startingPage "5370" @default.
- W4247434047 abstract "Abstract Light‐molecule strong coupling has emerged within the last decade as a new method to control chemical reactions. A few years ago it was discovered that chemical reactivity could be altered by vibrational strong coupling (VSC). Only a limited number of reactions have been investigated under VSC to date, including solvolysis and deprotection reactions. Here the effect of VSC on a series of aldehydes and ketones undergoing Prins cyclization, an important synthetic step in pharmaceutical chemistry, is investigated. A decrease of the second‐order rate constant with VSC of the reactant carbonyl stretching groups is observed. We also observe an increased activation energy due to VSC, but proportional changes in activation enthalpy and entropy, suggesting no substantive change in reaction pathway. The addition of common cycloaddition reactions to the stable of VSC‐modified chemical reactions is another step towards establishing VSC as a genuine tool for synthetic chemistry." @default.
- W4247434047 created "2022-05-12" @default.
- W4247434047 creator A5013832983 @default.
- W4247434047 creator A5017573959 @default.
- W4247434047 creator A5030741681 @default.
- W4247434047 creator A5061627729 @default.
- W4247434047 date "2020-02-18" @default.
- W4247434047 modified "2023-10-11" @default.
- W4247434047 title "Modulation of Prins Cyclization by Vibrational Strong Coupling" @default.
- W4247434047 cites W1967635014 @default.
- W4247434047 cites W1968758736 @default.
- W4247434047 cites W2032265388 @default.
- W4247434047 cites W2047485586 @default.
- W4247434047 cites W2049555701 @default.
- W4247434047 cites W2063874414 @default.
- W4247434047 cites W2148221544 @default.
- W4247434047 cites W2200146405 @default.
- W4247434047 cites W2315204504 @default.
- W4247434047 cites W2507492111 @default.
- W4247434047 cites W2514314815 @default.
- W4247434047 cites W2516953064 @default.
- W4247434047 cites W2519893846 @default.
- W4247434047 cites W2527620704 @default.
- W4247434047 cites W2533581290 @default.
- W4247434047 cites W2909675193 @default.
- W4247434047 cites W2909837409 @default.
- W4247434047 cites W2912574264 @default.
- W4247434047 cites W2949245623 @default.
- W4247434047 cites W2970795575 @default.
- W4247434047 cites W4237712874 @default.
- W4247434047 cites W4241909043 @default.
- W4247434047 cites W4243960545 @default.
- W4247434047 doi "https://doi.org/10.1002/ange.201915632" @default.
- W4247434047 hasPublicationYear "2020" @default.
- W4247434047 type Work @default.
- W4247434047 citedByCount "23" @default.
- W4247434047 countsByYear W42474340472020 @default.
- W4247434047 countsByYear W42474340472021 @default.
- W4247434047 countsByYear W42474340472022 @default.
- W4247434047 countsByYear W42474340472023 @default.
- W4247434047 crossrefType "journal-article" @default.
- W4247434047 hasAuthorship W4247434047A5013832983 @default.
- W4247434047 hasAuthorship W4247434047A5017573959 @default.
- W4247434047 hasAuthorship W4247434047A5030741681 @default.
- W4247434047 hasAuthorship W4247434047A5061627729 @default.
- W4247434047 hasBestOaLocation W42474340472 @default.
- W4247434047 hasConcept C121332964 @default.
- W4247434047 hasConcept C142724271 @default.
- W4247434047 hasConcept C147597530 @default.
- W4247434047 hasConcept C147789679 @default.
- W4247434047 hasConcept C148898269 @default.
- W4247434047 hasConcept C161790260 @default.
- W4247434047 hasConcept C177801218 @default.
- W4247434047 hasConcept C178790620 @default.
- W4247434047 hasConcept C185592680 @default.
- W4247434047 hasConcept C204787440 @default.
- W4247434047 hasConcept C2776910235 @default.
- W4247434047 hasConcept C2779293432 @default.
- W4247434047 hasConcept C2779664164 @default.
- W4247434047 hasConcept C3288061 @default.
- W4247434047 hasConcept C32909587 @default.
- W4247434047 hasConcept C62520636 @default.
- W4247434047 hasConcept C71924100 @default.
- W4247434047 hasConcept C75473681 @default.
- W4247434047 hasConcept C93391505 @default.
- W4247434047 hasConcept C94412978 @default.
- W4247434047 hasConcept C97355855 @default.
- W4247434047 hasConceptScore W4247434047C121332964 @default.
- W4247434047 hasConceptScore W4247434047C142724271 @default.
- W4247434047 hasConceptScore W4247434047C147597530 @default.
- W4247434047 hasConceptScore W4247434047C147789679 @default.
- W4247434047 hasConceptScore W4247434047C148898269 @default.
- W4247434047 hasConceptScore W4247434047C161790260 @default.
- W4247434047 hasConceptScore W4247434047C177801218 @default.
- W4247434047 hasConceptScore W4247434047C178790620 @default.
- W4247434047 hasConceptScore W4247434047C185592680 @default.
- W4247434047 hasConceptScore W4247434047C204787440 @default.
- W4247434047 hasConceptScore W4247434047C2776910235 @default.
- W4247434047 hasConceptScore W4247434047C2779293432 @default.
- W4247434047 hasConceptScore W4247434047C2779664164 @default.
- W4247434047 hasConceptScore W4247434047C3288061 @default.
- W4247434047 hasConceptScore W4247434047C32909587 @default.
- W4247434047 hasConceptScore W4247434047C62520636 @default.
- W4247434047 hasConceptScore W4247434047C71924100 @default.
- W4247434047 hasConceptScore W4247434047C75473681 @default.
- W4247434047 hasConceptScore W4247434047C93391505 @default.
- W4247434047 hasConceptScore W4247434047C94412978 @default.
- W4247434047 hasConceptScore W4247434047C97355855 @default.
- W4247434047 hasFunder F4320334704 @default.
- W4247434047 hasFunder F4320334764 @default.
- W4247434047 hasFunder F4320338111 @default.
- W4247434047 hasIssue "13" @default.
- W4247434047 hasLocation W42474340471 @default.
- W4247434047 hasLocation W42474340472 @default.
- W4247434047 hasLocation W42474340473 @default.
- W4247434047 hasLocation W42474340474 @default.
- W4247434047 hasOpenAccess W4247434047 @default.
- W4247434047 hasPrimaryLocation W42474340471 @default.