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- W4247483471 abstract "The chlorine−dioxide-tetrathionate reaction was studied spectrophotometrically in the pH range 4.55−5.55 at 25.0 ± 0.2 °C and 0.5 M ionic strength adjusted with sodium acetate as a buffer component. The stoichiometry was found to be S4O62- + 4•ClO2 + 5H2O → 4SO42- + ClO3- + 3Cl- + 10H+ with small deviations at high excess of chlorine dioxide with no chloride ion initially present. The initial presence of chloride not only affects the stoichiometry but also accelerates the reaction. A 14-step mechanism, including four known and two newly proposed intermediates, is suggested to describe the observed behavior of the system." @default.
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- W4247483471 date "2003-11-01" @default.
- W4247483471 modified "2023-09-27" @default.
- W4247483471 title "Kinetics and Mechanism of the Chlorine Dioxide-Tetrathionate Reaction" @default.
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- W4247483471 doi "https://doi.org/10.1021/jp0348629" @default.
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