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• W4247489787 abstract "A neutral C4 cumulene 1 that includes a cyclic alkyl(amino) carbene (cAAC), its air-stable radical cation 1.+, and dication 12+ have been synthesized. The redox property of 1.+ was studied by cyclic voltammetry. EPR and theoretical calculations show that the unpaired electron in 1.+ is mainly delocalized over the central C4 backbone. The commercially available CBr4 is utilized as a source of dicarbon in the cumulene synthesis." @default.
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• W4247489787 date "2014-03-12" @default.
• W4247489787 modified "2023-10-18" @default.
• W4247489787 title "C₄Cumulene and the Corresponding Air-Stable Radical Cation and Dication" @default.
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• W4247489787 doi "https://doi.org/10.1002/ange.201310975" @default.
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