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- W4247526362 abstract "Cyclische pseudopeptidische Thiosulfinate folgen einem neuen Reaktionsmodus, der in biologischen Systemen bedeutsam sein könnte. Dabei wird die S(O)-S-Bindung von 1 hydrolytisch gespalten, und durch Metallierung entsteht der dissymmetrische CoIII-Komplex 2 mit Diamidato-N-, Thiolato-S- und Sulfinato-S-Donoren, der dem aktiven Zentrum von Nitrilhydratase ähnlich ist. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2005/z500814_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4247526362 date "2005-09-20" @default.
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- W4247526362 title "Direct Synthesis of a Thiolato-S and Sulfinato-S CoIII Complex Related to the Active Site of Nitrile Hydratase: A Pathway to the Post-Translational Oxidation of the Protein" @default.
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- W4247526362 doi "https://doi.org/10.1002/ange.200500814" @default.
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