FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4247528745> ?p ?o ?g. }

• W4247528745 endingPage "2351" @default.
• W4247528745 startingPage "2342" @default.
• W4247528745 abstract "The complexes [LtBuNi(OCO-κ2O,C)]M3[N(SiMe3)2]2 (M=Li, Na, K), synthesized by deprotonation of a nickel formate complex [LtBuNiOOCH] with the corresponding amides M[N(SiMe3)2], feature a NiII−CO22− core surrounded by Lewis-acidic cations (M+) and the influence of the latter on the behavior and reactivity was studied. The results point to a decrease of CO2 activation within the series Li, Na, and K, which is also reflected in the reactivity with Me3SiOTf leading to the liberation of CO and formation of a Ni−OSiMe3 complex. Furthermore, in case of K+, the {[K3[N(SiMe3)2]2}+ shell around the Ni−CO22− entity was shown to have a large impact on its stabilization and behavior. If the number of K[N(SiMe3)2] equivalents used in the reaction with [LtBuNiOOCH] is decreased from 3 to 0.5, the deprotonated part of the precursor enters a complex reaction sequence with formation of [LtBuNiI(μ-OOCH)NiILtBu]K and [LtBuNi(C2O4)NiLtBu]. The same reaction at higher concentrations additionally led to the formation of a unique hexanuclear NiII complex containing both oxalate and mesoxalate ([O2C-CO2-CO2]4−) ligands." @default.
• W4247528745 created "2022-05-12" @default.
• W4247528745 creator A5014270872 @default.
• W4247528745 creator A5048726558 @default.
• W4247528745 creator A5060390678 @default.
• W4247528745 creator A5062527317 @default.
• W4247528745 creator A5068979603 @default.
• W4247528745 creator A5069306404 @default.
• W4247528745 creator A5088076659 @default.
• W4247528745 date "2020-11-30" @default.
• W4247528745 modified "2023-10-16" @default.
• W4247528745 title "Selective Transformation of Nickel‐Bound Formate to CO or C−C Coupling Products Triggered by Deprotonation and Steered by Alkali‐Metal Ions" @default.
• W4247528745 cites W1509205489 @default.
• W4247528745 cites W1932228583 @default.
• W4247528745 cites W1966109379 @default.
• W4247528745 cites W1971101431 @default.
• W4247528745 cites W1976125347 @default.
• W4247528745 cites W1977604128 @default.
• W4247528745 cites W1992704655 @default.
• W4247528745 cites W2001998865 @default.
• W4247528745 cites W2005320801 @default.
• W4247528745 cites W2007379539 @default.
• W4247528745 cites W2008182925 @default.
• W4247528745 cites W2009436238 @default.
• W4247528745 cites W2011341872 @default.
• W4247528745 cites W2016821405 @default.
• W4247528745 cites W2020991928 @default.
• W4247528745 cites W2025118032 @default.
• W4247528745 cites W2026712828 @default.
• W4247528745 cites W2028232902 @default.
• W4247528745 cites W2037837120 @default.
• W4247528745 cites W2039786475 @default.
• W4247528745 cites W2061939602 @default.
• W4247528745 cites W2079195039 @default.
• W4247528745 cites W2081487037 @default.
• W4247528745 cites W2085797090 @default.
• W4247528745 cites W2097188154 @default.
• W4247528745 cites W2108812250 @default.
• W4247528745 cites W2121401391 @default.
• W4247528745 cites W2125720063 @default.
• W4247528745 cites W2126167196 @default.
• W4247528745 cites W2132654860 @default.
• W4247528745 cites W2140182426 @default.
• W4247528745 cites W2169363855 @default.
• W4247528745 cites W2246944211 @default.
• W4247528745 cites W2274366216 @default.
• W4247528745 cites W2520778196 @default.
• W4247528745 cites W2520926667 @default.
• W4247528745 cites W2611869399 @default.
• W4247528745 cites W2725648806 @default.
• W4247528745 cites W2761818913 @default.
• W4247528745 cites W2761959175 @default.
• W4247528745 cites W2769456954 @default.
• W4247528745 cites W2783599016 @default.
• W4247528745 cites W2786051018 @default.
• W4247528745 cites W2796469387 @default.
• W4247528745 cites W2797853918 @default.
• W4247528745 cites W2801258549 @default.
• W4247528745 cites W2801547568 @default.
• W4247528745 cites W2804905207 @default.
• W4247528745 cites W2806391628 @default.
• W4247528745 cites W2811449630 @default.
• W4247528745 cites W2884851374 @default.
• W4247528745 cites W2888903515 @default.
• W4247528745 cites W2897457097 @default.
• W4247528745 cites W2900735309 @default.
• W4247528745 cites W2947239187 @default.
• W4247528745 cites W2950295031 @default.
• W4247528745 cites W2953350983 @default.
• W4247528745 cites W2984001042 @default.
• W4247528745 cites W3015279577 @default.
• W4247528745 cites W3139224641 @default.
• W4247528745 cites W4239326526 @default.
• W4247528745 cites W4242828387 @default.
• W4247528745 cites W4248029352 @default.
• W4247528745 doi "https://doi.org/10.1002/ange.202010180" @default.
• W4247528745 hasPublicationYear "2020" @default.
• W4247528745 type Work @default.
• W4247528745 citedByCount "3" @default.
• W4247528745 countsByYear W42475287452023 @default.
• W4247528745 crossrefType "journal-article" @default.
• W4247528745 hasAuthorship W4247528745A5014270872 @default.
• W4247528745 hasAuthorship W4247528745A5048726558 @default.
• W4247528745 hasAuthorship W4247528745A5060390678 @default.
• W4247528745 hasAuthorship W4247528745A5062527317 @default.
• W4247528745 hasAuthorship W4247528745A5068979603 @default.
• W4247528745 hasAuthorship W4247528745A5069306404 @default.
• W4247528745 hasAuthorship W4247528745A5088076659 @default.
• W4247528745 hasBestOaLocation W42475287452 @default.
• W4247528745 hasConcept C118629725 @default.
• W4247528745 hasConcept C142724271 @default.
• W4247528745 hasConcept C145148216 @default.
• W4247528745 hasConcept C155647269 @default.
• W4247528745 hasConcept C161790260 @default.
• W4247528745 hasConcept C178790620 @default.
• W4247528745 hasConcept C179104552 @default.
• W4247528745 hasConcept C185592680 @default.
• W4247528745 hasConcept C198091228 @default.

• next