Matches in SemOpenAlex for { <https://semopenalex.org/work/W4247550982> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W4247550982 endingPage "N22" @default.
- W4247550982 startingPage "N21" @default.
- W4247550982 abstract "Reaction of PhHgOAc with N-NHCOC6H5–Htpp gave a bismercury(II) complex [((benzamido-κN)phenylmercury-κHg–N21,N22)-meso-tetraphenylporphyrinato-N23,N24]phenylmercury(II) toluene solvate [Hg(Ph)(N21,N22–(Ph)–Hg–N(COPh)tpp · C6H5CH3; 3 · C6H5CH3] with Hg(1)–N(5) as N21,N22-bridged atoms. The crystal structure of 3 · C6H5CH3 was determined. The Hg(1)⋯Hg(2) distance is 3.611(7) Å. Hence, no metallophilic Hg(II)⋯Hg(II) interaction is present. 3 in CDCl3 was characterized by 1H, 13C, and 199Hg NMR. The 199Hg NMR spectrum for 3 in CDCl3 solution 20 °C clearly reveals that there are two different Hg nuclei, i.e. Hg(1) and Hg(2) and this NMR data provides an evidence that 3 remains as a bismercury species in CDCl3 solution. The 199Hg NMR spectrum for a 0.2 M solution of 3 in CDCl3 at 20 °C is observed at −1088 ppm for Hg(2) nucleus with 3J(Hg–H) = 188 Hz and an effective coordination number of five and at −1119 ppm for Hg(1) nucleus with 3J(Hg–H) = 177 Hz and an effective coordination number of four. The proton and 199Hg NMR spectra clearly show 3J(Hg–H) coupling and these NMR data indicate no ligand exchange for 3 in CDCl3." @default.
- W4247550982 created "2022-05-12" @default.
- W4247550982 date "1993-02-05" @default.
- W4247550982 modified "2023-09-26" @default.
- W4247550982 title "Environmental catalysis" @default.
- W4247550982 doi "https://doi.org/10.1016/0926-860x(93)85016-i" @default.
- W4247550982 hasPublicationYear "1993" @default.
- W4247550982 type Work @default.
- W4247550982 citedByCount "0" @default.
- W4247550982 crossrefType "journal-article" @default.
- W4247550982 hasConcept C103319777 @default.
- W4247550982 hasConcept C111429119 @default.
- W4247550982 hasConcept C115624301 @default.
- W4247550982 hasConcept C116569031 @default.
- W4247550982 hasConcept C121332964 @default.
- W4247550982 hasConcept C1276947 @default.
- W4247550982 hasConcept C147789679 @default.
- W4247550982 hasConcept C155647269 @default.
- W4247550982 hasConcept C170493617 @default.
- W4247550982 hasConcept C178790620 @default.
- W4247550982 hasConcept C185592680 @default.
- W4247550982 hasConcept C2778142098 @default.
- W4247550982 hasConcept C4839761 @default.
- W4247550982 hasConcept C55493867 @default.
- W4247550982 hasConcept C66974803 @default.
- W4247550982 hasConcept C67787023 @default.
- W4247550982 hasConcept C71240020 @default.
- W4247550982 hasConcept C8010536 @default.
- W4247550982 hasConceptScore W4247550982C103319777 @default.
- W4247550982 hasConceptScore W4247550982C111429119 @default.
- W4247550982 hasConceptScore W4247550982C115624301 @default.
- W4247550982 hasConceptScore W4247550982C116569031 @default.
- W4247550982 hasConceptScore W4247550982C121332964 @default.
- W4247550982 hasConceptScore W4247550982C1276947 @default.
- W4247550982 hasConceptScore W4247550982C147789679 @default.
- W4247550982 hasConceptScore W4247550982C155647269 @default.
- W4247550982 hasConceptScore W4247550982C170493617 @default.
- W4247550982 hasConceptScore W4247550982C178790620 @default.
- W4247550982 hasConceptScore W4247550982C185592680 @default.
- W4247550982 hasConceptScore W4247550982C2778142098 @default.
- W4247550982 hasConceptScore W4247550982C4839761 @default.
- W4247550982 hasConceptScore W4247550982C55493867 @default.
- W4247550982 hasConceptScore W4247550982C66974803 @default.
- W4247550982 hasConceptScore W4247550982C67787023 @default.
- W4247550982 hasConceptScore W4247550982C71240020 @default.
- W4247550982 hasConceptScore W4247550982C8010536 @default.
- W4247550982 hasIssue "2" @default.
- W4247550982 hasLocation W42475509821 @default.
- W4247550982 hasOpenAccess W4247550982 @default.
- W4247550982 hasPrimaryLocation W42475509821 @default.
- W4247550982 hasRelatedWork W1903409884 @default.
- W4247550982 hasRelatedWork W1971917763 @default.
- W4247550982 hasRelatedWork W2014744198 @default.
- W4247550982 hasRelatedWork W2039983385 @default.
- W4247550982 hasRelatedWork W2097069997 @default.
- W4247550982 hasRelatedWork W2099799946 @default.
- W4247550982 hasRelatedWork W2131219719 @default.
- W4247550982 hasRelatedWork W2154339252 @default.
- W4247550982 hasRelatedWork W2616297787 @default.
- W4247550982 hasRelatedWork W4232354193 @default.
- W4247550982 hasVolume "94" @default.
- W4247550982 isParatext "false" @default.
- W4247550982 isRetracted "false" @default.
- W4247550982 workType "article" @default.