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- W4247667236 abstract "The reaction between potassium derivative {[(4-ButC6H4)2CH]−K+}n and alkyl iodides gives new 1,1-bis(4-tert-butylphenyl)alkanes which can be deprotonated with BunNa to produce species [(4-ButC6H4)2CR]−Na+ (R = Me, Bui). The salt metathesis of the latter with base-free CaI2 or YbI2 affords novel bis(hydrocarbyl) complexes [(4-ButC6H4)2CR]2M(TMEDA) (M = Ca, R = Me; M = Yb, R = Bui). The hyperconjugation of the central carbanion with alkyl groups pronouncedly enhances the basic properties of the compounds which would perform CH bond activation in toluene and thiophene, in distinction to the related ‘nonalkylated’ analogues with (4-ButC6H4)2CH− ligand." @default.
- W4247667236 created "2022-05-12" @default.
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- W4247667236 date "2021-05-01" @default.
- W4247667236 modified "2023-10-16" @default.
- W4247667236 title "Highly basic alkyl-substituted bis(benzhydryl) CaII and YbII complexes with β-CH–M agostic interactions" @default.
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- W4247667236 doi "https://doi.org/10.1016/j.mencom.2021.05.017" @default.
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