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- W4247694145 abstract "The low temperature (–100 °C) X-ray structure of the complex K2[Yb(DTPA)(H2O)] has been determined. The metal ion is at the center of a tricapped trigonal prism and is nine-coordinate, binding to the three nitrogens and five oxygens of the ligand and one water molecule. From the structure obtained, three well-defined hydration shells can be observed consisting of: i) one coordinated water molecule; ii) several water molecules in the outer coordination sphere of the YbIII ion and iii) one water molecule surprisingly close to the metal center and hydrogen-bonded to proximate carboxylate groups. A variable-field and temperature NMRD study of the corresponding Gd complex has been performed and the data interpreted by taking into account the presence of second-sphere water molecule(s). The results of the analysis are in excellent agreement with the X-ray structural data." @default.
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- W4247694145 date "2000-05-01" @default.
- W4247694145 modified "2023-10-16" @default.
- W4247694145 title "Experimental Evidence for a Second Coordination Sphere Water Molecule in the Hydration Structure of YbDTPA – Insights for a Re-Assessment of the Relaxivity Data of GdDTPA" @default.
- W4247694145 doi "https://doi.org/10.1002/(sici)1099-0682(200005)2000:5<971::aid-ejic971>3.3.co;2-a" @default.
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