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- W4247722310 abstract "The electrochemical oxidation of 4-thiouracil (4TU) and 4-thiouridine (4TUr), which give one voltammetric peak at the pyrolytic graphite electrode (p.g.e.), has been investigated by linear sweep and cyclic voltammetry, macroscale electrolysis and product analysis. Oxidation of 4TU and 4TUr is an irreversible 1 e−, 1 H+ process leading to formation of free radicals which rapidly dimerize to bis(4-thiouracil)disulfide (DIS) or its riboside analog (rDIS). These disulfides can be readily electrochemically reduced back to the parent compounds. They also undergo spontaneous transformations in aqueous solution to various products, including the corresponding derivatives of 4TU, uracil, sulfenic acid and thiosulfonate, depending on pH and the presence of oxygen. The possible biological meaning of the results reported is discussed." @default.
- W4247722310 created "2022-05-12" @default.
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- W4247722310 date "1983-04-01" @default.
- W4247722310 modified "2023-09-27" @default.
- W4247722310 title "Electrochemical oxidation of 4-thiouracil to bis(4-thiouracil)disulfide and chemical transformations of the disulfide" @default.
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- W4247722310 doi "https://doi.org/10.1016/0302-4598(83)85079-x" @default.
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