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- W4247745764 abstract "Abstract Lewis‐acid catalysis and electrochemistry represent two powerful fields that have found widespread application in organic chemistry. Reported herein is an asymmetric electrosynthesis in combination with a chiral Ni catalyst leading to an intermolecular alkylation reaction in good yields with excellent enantioselectivities (up to 97 % ee ). Mechanistic studies suggest that the Lewis‐acid‐bound radical intermediate from a single‐electron anodic oxidation selectively reacts with the benzylic radical species to generate the desired adducts." @default.
- W4247745764 created "2022-05-12" @default.
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- W4247745764 date "2019-04-10" @default.
- W4247745764 modified "2023-10-05" @default.
- W4247745764 title "Asymmetric Lewis Acid Catalyzed Electrochemical Alkylation" @default.
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- W4247745764 doi "https://doi.org/10.1002/ange.201901801" @default.
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