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• W4247982665 abstract "Abstract Seven new prenylated indole alkaloids, taichunamides A–G, were isolated from the fungus Aspergillus taichungensis (IBT 19404). Taichunamides A and B contained an azetidine and 4‐pyridone units, respectively, and are likely biosynthesized from notoamide S via (+)‐6‐epi‐stephacidin A. Taichunamides C and D contain endoperoxide and methylsulfonyl units, respectively. This fungus produced indole alkaloids containing an anti ‐bicyclo[2.2.2]diazaoctane core, whereas A. protuberus and A. amoenus produced congeners with a syn ‐bicyclo[2.2.2]diazaoctane core. Plausible biosynthetic pathways to access these cores within the three species likely arise from an intramolecular hetero Diels–Alder reaction." @default.
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• W4247982665 date "2015-12-08" @default.
• W4247982665 modified "2023-09-26" @default.
• W4247982665 title "Taichunamides: Prenylated Indole Alkaloids from <i>Aspergillus taichungensis</i> (IBT 19404)" @default.
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• W4247982665 doi "https://doi.org/10.1002/ange.201509462" @default.
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