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- W4247996910 abstract "Triphenylselenonium chloride, (C3H5)3SeCl, is synthesized, its polarographic studies are made, andfound that its wave is composed of a two-step wave, i.e., the first wave is shown at half-wave potential of-0.93V(vs.S.C.E.)and the second wave at-1.11V(vs.S.C.E.);the half-wave potential of the second wave was found to move with the change of pH, From the observation of polarograms, the reactions of the first and second waves at the electrode are considered to be as follows:(C6H5)3SeC1+2e→(C6H5)2Se+C6H5C1(C6H5)2Se+2e+2H+→Se+2C6H6Studies on the mode of formation of precipitates of various metal ions with the use of this reagent are made and found that it is very sensitive as a reagent for qualitative detection of bismuth ion in the presence of iodide ion, The nature of action of this reagent against bismuth ion is studied by use of polarography and amperometric titration, and the same conclusion is reached as to the mechanismof precipitation reaction as given in the first report of this series." @default.
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- W4247996910 date "1954-01-01" @default.
- W4247996910 modified "2023-10-12" @default.
- W4247996910 title "Studies on the Analytical Applications of Onium Compounds.II." @default.
- W4247996910 doi "https://doi.org/10.2116/bunsekikagaku.3.199" @default.
- W4247996910 hasPublicationYear "1954" @default.
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