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• W4248021352 abstract "The reaction of a cyclic disilylated bromostibine with magnesium yields a rare example of a magnesium stibide that can be silylated with trimethylchlorosilane. Reaction of the thus-obtained trisilylated stibine with potassium tert-butoxide gives a potassium stibide in a clean reaction. Attempts to obtain an antimony-containing oligosilanide did not lead to the expected compound but to another potassium stibide, which presumably forms from the initially formed silanide by a 1,2-silyl shift. The synthetic potential of the obtained stibides to serve as building blocks could be shown by the preparation of stibylated zircono- and hafnocenes." @default.
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• W4248021352 date "2015-04-10" @default.
• W4248021352 modified "2023-10-16" @default.
• W4248021352 title "Metalated Oligosilanylstibines" @default.
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• W4248021352 doi "https://doi.org/10.1021/om501297h" @default.
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