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- W4248068166 abstract "The high efficiency and mild reaction conditions associated with the Cu(I) catalyzed cycloaddition of azides and alkynes were exploited for the covalent layer-by-layer synthesis of dendritic thin films on silicon wafers. The layer-by-layer self assembly process proceeds under ambient conditions and was monitored by ellipsometry, XPS and ATR-IR which showed extremely regular growth of the dendritic thin films. Film thickness could be accurately controlled by both the size/generation number of the dendrimers as well as the number of layers. In comparison with linear analogues, the growth of the dendritic films was significantly more controlled and defect-free with each layer being thinner than the corresponding films prepared from the isomeric linear polymers, demonstrating the well-defined, 3-dimensional nature of the dendritic architecture." @default.
- W4248068166 created "2022-05-12" @default.
- W4248068166 date "2007-07-15" @default.
- W4248068166 modified "2023-10-16" @default.
- W4248068166 doi "https://doi.org/10.1002/pola.v45:14" @default.
- W4248068166 hasPublicationYear "2007" @default.
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