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• W4248179987 endingPage "16308" @default.
• W4248179987 startingPage "16305" @default.
• W4248179987 abstract "We report a monometallic dysprosium complex, [Dy(OtBu)2(py)5][BPh4] (5), that shows the largest effective energy barrier to magnetic relaxation of Ueff=1815(1) K. The massive magnetic anisotropy is due to bis-trans-disposed tert-butoxide ligands with weak equatorial pyridine donors, approaching proposed schemes for high-temperature single-molecule magnets (SMMs). The blocking temperature, TB , is 14 K, defined by zero-field-cooled magnetization experiments, and is the largest for any monometallic complex and equal with the current record for [Tb2N2{N(SiMe3)2}4(THF)2]." @default.
• W4248179987 created "2022-05-12" @default.
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• W4248179987 date "2016-11-22" @default.
• W4248179987 modified "2023-09-30" @default.
• W4248179987 title "On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet" @default.
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• W4248179987 doi "https://doi.org/10.1002/ange.201609685" @default.
• W4248179987 hasPublicationYear "2016" @default.
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