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- W4248183902 abstract "Fix gebunden: Anders als cyclische Diaminocarbene reagieren stabile Alkylaminocarbene mit CO zu stabilen Ketenen (Schema oben). Im Unterschied zu den acyclischen Derivaten können cyclische Aminoketene der destabilisierenden n-π-Donorfunktion des freien N-Elektronenpaars nicht ausweichen, was zu einem Diradikalcharakter und ungewöhnlichen optischen (Schema unten und Photos von Kristallen) wie NMR-spektroskopischen Eigenschaften führt. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z600987_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W4248183902 created "2022-05-12" @default.
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- W4248183902 date "2006-05-10" @default.
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- W4248183902 title "CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap" @default.
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- W4248183902 doi "https://doi.org/10.1002/ange.200600987" @default.
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