Matches in SemOpenAlex for { <https://semopenalex.org/work/W4248201092> ?p ?o ?g. }
- W4248201092 endingPage "7903" @default.
- W4248201092 startingPage "7897" @default.
- W4248201092 abstract "Abstract A palladium‐catalyzed cross‐coupling between in situ generated allenyl/propargyl‐lithium species and aryl bromides to yield highly functionalized allenes is reported. The direct and selective formation of allenic products preventing the corresponding isomeric propargylic product is accomplished by the choice of SPhos or XPhos based Pd catalysts. The methodology avoids the prior transmetalation to other transition metals or reverse approaches that required prefunctionalization of substrates with leaving groups, resulting in a fast and efficient approach for the synthesis of tri‐ and tetrasubstituted allenes. Experimental and theoretical studies on the mechanism show catalyst control of selectivity in this allene formation." @default.
- W4248201092 created "2022-05-12" @default.
- W4248201092 creator A5052232106 @default.
- W4248201092 creator A5078954465 @default.
- W4248201092 creator A5079668118 @default.
- W4248201092 creator A5087713906 @default.
- W4248201092 date "2020-03-13" @default.
- W4248201092 modified "2023-09-24" @default.
- W4248201092 title "Synthesis and Functionalization of Allenes by Direct Pd‐Catalyzed Organolithium Cross‐Coupling" @default.
- W4248201092 cites W1966866254 @default.
- W4248201092 cites W1968264086 @default.
- W4248201092 cites W1978263407 @default.
- W4248201092 cites W1986573080 @default.
- W4248201092 cites W1988091937 @default.
- W4248201092 cites W1990166503 @default.
- W4248201092 cites W1994054637 @default.
- W4248201092 cites W1996291394 @default.
- W4248201092 cites W2001246827 @default.
- W4248201092 cites W2008112166 @default.
- W4248201092 cites W2015577073 @default.
- W4248201092 cites W2020121987 @default.
- W4248201092 cites W2022935736 @default.
- W4248201092 cites W2030387893 @default.
- W4248201092 cites W2034358928 @default.
- W4248201092 cites W2039315929 @default.
- W4248201092 cites W2042609757 @default.
- W4248201092 cites W2045906370 @default.
- W4248201092 cites W2053556296 @default.
- W4248201092 cites W2056522155 @default.
- W4248201092 cites W2058795528 @default.
- W4248201092 cites W2071359115 @default.
- W4248201092 cites W2079840418 @default.
- W4248201092 cites W2081549829 @default.
- W4248201092 cites W2083496413 @default.
- W4248201092 cites W2089794429 @default.
- W4248201092 cites W2097998103 @default.
- W4248201092 cites W2109499088 @default.
- W4248201092 cites W2117454916 @default.
- W4248201092 cites W2123695505 @default.
- W4248201092 cites W2126477640 @default.
- W4248201092 cites W2127603052 @default.
- W4248201092 cites W2138596549 @default.
- W4248201092 cites W2140026331 @default.
- W4248201092 cites W2140889506 @default.
- W4248201092 cites W2143119541 @default.
- W4248201092 cites W2146862414 @default.
- W4248201092 cites W2150195378 @default.
- W4248201092 cites W2154098641 @default.
- W4248201092 cites W2154511358 @default.
- W4248201092 cites W2163387799 @default.
- W4248201092 cites W2164639897 @default.
- W4248201092 cites W2221076464 @default.
- W4248201092 cites W2259039721 @default.
- W4248201092 cites W2282338350 @default.
- W4248201092 cites W2318213185 @default.
- W4248201092 cites W2462357926 @default.
- W4248201092 cites W2489824448 @default.
- W4248201092 cites W2607693203 @default.
- W4248201092 cites W2622699432 @default.
- W4248201092 cites W2787548495 @default.
- W4248201092 cites W2903495452 @default.
- W4248201092 cites W2904364546 @default.
- W4248201092 cites W2910528938 @default.
- W4248201092 cites W2921502723 @default.
- W4248201092 cites W2922208716 @default.
- W4248201092 cites W2937553258 @default.
- W4248201092 cites W2944233069 @default.
- W4248201092 cites W2944433935 @default.
- W4248201092 cites W2944619666 @default.
- W4248201092 cites W2949252648 @default.
- W4248201092 cites W2949742340 @default.
- W4248201092 cites W2951339013 @default.
- W4248201092 cites W2952987318 @default.
- W4248201092 cites W2953236268 @default.
- W4248201092 cites W2967218838 @default.
- W4248201092 cites W4235246641 @default.
- W4248201092 cites W4242338383 @default.
- W4248201092 cites W4254794596 @default.
- W4248201092 cites W652900620 @default.
- W4248201092 doi "https://doi.org/10.1002/ange.201913132" @default.
- W4248201092 hasPublicationYear "2020" @default.
- W4248201092 type Work @default.
- W4248201092 citedByCount "4" @default.
- W4248201092 countsByYear W42482010922020 @default.
- W4248201092 crossrefType "journal-article" @default.
- W4248201092 hasAuthorship W4248201092A5052232106 @default.
- W4248201092 hasAuthorship W4248201092A5078954465 @default.
- W4248201092 hasAuthorship W4248201092A5079668118 @default.
- W4248201092 hasAuthorship W4248201092A5087713906 @default.
- W4248201092 hasBestOaLocation W42482010922 @default.
- W4248201092 hasConcept C115537861 @default.
- W4248201092 hasConcept C118792377 @default.
- W4248201092 hasConcept C134018914 @default.
- W4248201092 hasConcept C134121241 @default.
- W4248201092 hasConcept C142653250 @default.
- W4248201092 hasConcept C147789679 @default.
- W4248201092 hasConcept C161790260 @default.
- W4248201092 hasConcept C178790620 @default.