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- W4248281623 abstract "Abstract An ammonium‐containing metal iodate fluoride compound, (NH 4 )Bi 2 (IO 3 ) 2 F 5 , featuring a two‐dimensional double‐layered framework constructed by [BiO 2 F 5 ] 6− and [BiO 4 F 4 ] 9− polyhedra, as well as [IO 3 ] − groups, was successfully synthesized. The well‐ordered alignment of these SHG‐active units leads to an extraordinary strong SHG response of 9.2 times that of KDP. Moreover, this compound possesses a large birefringence (Δ n =0.0690 at 589.3 nm), a wide energy band gap ( E g =3.88 eV), and a high laser damage threshold (LDT; 40.2×AgGaS 2 ). In particular, thermochromic behavior was observed for the first time in this type of compound. Such multifunctional crystals will expand the application of nonlinear optical materials." @default.
- W4248281623 created "2022-05-12" @default.
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- W4248281623 date "2020-01-09" @default.
- W4248281623 modified "2023-10-13" @default.
- W4248281623 title "(NH 4 )Bi 2 (IO 3 ) 2 F 5 : An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior" @default.
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- W4248281623 doi "https://doi.org/10.1002/ange.201913287" @default.
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