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- W4248285986 abstract "Dimethylmetaldiazocompounds Me2MC(N2)R (R = CO2Et; Me2M), have been prepared from the corresponding metal amides Me2MNR1R2; they were characterized by elemental analyses, IR and NMR spectroscopy. The carbon atom in organometallic diazoalkanes of antimony and bismith is more nucleophilic than that in organic diazoalkanes as proved by 13C NMR spectra. Attempts to obtain Me2AsCHN2 failed; the formation of bis(dialkylmetalyl)diazomethanes (R2M)2CN2 seems to be favoured in all cases. Dimethylmetall-diazoverbindungen Me2MC(N2)R (R = CO2Et, Me2M), wurden den aus den entsprechenden Metallamiden Me2NMR1R2 dargestellt; sie wurden durch Elementaranalysen, IR- und NMR-Spektroskopie charakterisiert. Das Kohlenstoffatom in metallorganischen Diazoalkanen von Antimon und Wismut ist nucleophiler als in organischen Diazoalkanen wie durch 13C-NMR-Spektren gezeigt werden konnte. Versusche, Me2AsCHN2 zu erhalten, schlugen fehl; die Bildung von Bis(dialkylmetalyl)diazomethanen (R2M)2CN2 scheint in allen Fällen begünstigt zu sein." @default.
- W4248285986 created "2022-05-12" @default.
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- W4248285986 date "1975-07-01" @default.
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- W4248285986 title "Metallorganische diazoverbindungen" @default.
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- W4248285986 doi "https://doi.org/10.1016/s0022-328x(00)94007-5" @default.
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