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- W4248520154 abstract "Ein Stups genügt (in Form von Kieselgel, einem sauren Ionenaustauscherharz oder Erwärmen auf etwa 40 °C), damit die Acetatderivate enantiomerenangereicherter Cyclopropenylalkohole eine sigmatrope Umlagerung mit hohen ee-Werten zu Alkylidencyclopropanen eingehen (siehe Schema). Analog führt die Umlagerung von Phosphinitderivaten bei Raumtemperatur zu Phosphanoxid-Vorstufen ungewöhnlicher chiraler Phosphanliganden. R1, R2=Alkyl, Aryl." @default.
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- W4248520154 date "2007-10-22" @default.
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- W4248520154 title "An Efficient, Facile, and General Stereoselective Synthesis of Heterosubstituted Alkylidenecyclopropanes" @default.
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- W4248520154 doi "https://doi.org/10.1002/ange.200702713" @default.
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