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- W4248563205 abstract "Abstract An aliphatic polyester has been prepared from ethylene oxide and maleic anhydride that undergoes reversible transformation between amorphous (T g =18 °C) and crystalline (T m =124 °C) states through cis–trans isomerization of the C=C bonds in the polymer backbone without any change in either the molecular weight or dispersity of the polymer. A similar transformation was also observed in chiral unsaturated polyesters formed from enantiopure terminal epoxides, such as epichlorohydrin, phenyl glycidyl ether, and (2,3‐epoxypropyl)benzene. These unsaturated polyesters with 100 % E ‐configuration in the crystalline state were prepared by quantitative isomerization of their Z ‐configuration analogues in the presence of a catalytic amount of diethylamine, while in the presence of benzophenone, irradiation with 365 nm UV light resulted in the transformation of about 30 % trans ‐alkene to cis ‐maleate form, thereby affording amorphous polyesters." @default.
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- W4248563205 date "2019-10-30" @default.
- W4248563205 modified "2023-09-27" @default.
- W4248563205 title "Reversible Transformation between Amorphous and Crystalline States of Unsaturated Polyesters by <i>Cis</i> – <i>Trans</i> Isomerization" @default.
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- W4248563205 doi "https://doi.org/10.1002/ange.201910369" @default.
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