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- W4248765918 abstract "[97-93-8] C6H15Al (MW 114.19) InChI = 1S/3C2H5.Al/c3*1-2;/h3*1H2,2H3; InChIKey = VOITXYVAKOUIBA-UHFFFAOYSA-N (Lewis acid and source of hydride38-40 and nucleophilic ethyl group;2-5, 22, 33 couples with alkenyl halides in the presence of a transition metal catalyst;8-11 selective hydrocyanation agent in combination with TMSCN14 or HCN;12, 15, 41 promoter of alkylation other than ethylation;16, 42-44 cyclopropanation agent;21, 45, 46 polymerization cocatalyst47) Physical Data: mp −58 °C; bp 62 °C/0.8 mmHg; d 0.835 g cm−3 (25 °C). Solubility: freely miscible with saturated and aromatic hydrocarbons; reacts violently with H2O and protic solvents. Form Supplied in: as a neat liquid in a stainless container or as a solution in hydrocarbon solvents (hexane, heptane, toluene). Analysis of Reagent Purity: brochures from manufacturers, describe an apparatus and method for assay. Handling, Storage, and Precautions: indefinitely stable under an inert atmosphere. The neat liquid or dense solutions are highly pyrophoric. Solutions more dilute than a certain concentration are not pyrophoric and are safer to handle. The nonpyrophoric limits are 13 wt % in isopentane, 12 wt % in hexane, and 12 wt % in heptane, respectively. Use of halogenated hydrocarbons as solvents should be avoided because of possible explosive reactions sometimes observed for mixtures of CCl4 and organoaluminums." @default.
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- W4248765918 date "2007-03-15" @default.
- W4248765918 modified "2023-09-23" @default.
- W4248765918 title "Triethylaluminum" @default.
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- W4248765918 doi "https://doi.org/10.1002/047084289x.rt216.pub2" @default.
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