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- W4248858430 abstract "We present a scaling model of hydrophobic polyelectrolytes. In dilute salt-free solutions these polymers have a necklacelike shape with compact beads joined by narrow strings. This necklacelike structure manifests itself in the unique scaling laws in semidilute regime for the concentration range where the correlation length ξ of a solution is on the order of the string length between two neighboring beads. In this regime the correlation length ξ decreases with polymer concentration c as ξ ∼ c-1/3, viscosity is concentration independent, and self-diffusion coefficient D increases with concentration D ∼ c1/3 in both unentangled and entangled solutions. The effects of added salt on the properties of hydrophobic polyelectrolyte solutions are also discussed." @default.
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- W4248858430 date "1999-01-21" @default.
- W4248858430 modified "2023-10-14" @default.
- W4248858430 title "Hydrophobic Polyelectrolytes" @default.
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- W4248858430 doi "https://doi.org/10.1021/ma981412j" @default.
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